copper sulfide phases

The copper sulfide crystal structure plays a key role in the mechanism by which cation exchange occurs and the product that forms. Copper sulfide has been prepared by a number of different routes, 16 such as the ubiquitous hot-injection method, 2,4,17−20 solvothermal synthesis, 21 and cation exchange. (Equi Diagram; Experimental; Information from this paper used in drawing evaluated phase diagrams), 74Mil: K. C. Mills,Thermodynamic Data for Inorganic Sulphides, Selenides and Tellurides, Butterworths, London (1974). Whatever their source, copper sulfides vary widely in composition with 0.5 ≤ Cu/S ≤ 2, including numerous non-stoichiometric compounds. (Equi Diagram; Experimental), 38Smi: C.S. (Meta Phases; Experimental), 74Bur: B. P. Burylev, N. N. Fedorova, and L. Sh. It produces a compound called copper sulfide. G. (Equi Diagram; Experimental; Indicates presence of a phase diagram), 49Ued: R. Ueda, “X-ray and Thermal Studies of Phase Transformations of Cuprous Sulfide”,J. (Equi Diagram; Experimental), 74Dum: A. Dumon, A. Lichanot, and S. Gromb, “Study of Cu-S Phase Diagram in Compositional Area Cu2.000S-Cu1.960S”,J. Copper sulfide solid phases display size-related voltammetric behavior at Hg electrodes. Bulletin of Alloy Phase Diagrams (Thermo; Compilation), 73Mul: B. J. Mulder, “Protodjurleite, a Metastable Form of Cuprous Sulfide”,Krist. (Crys Structure; Experimental), Indicates key paper36Rah: P. Rahlfs, “Cubic High Temperature Modifications of Sulfides, Selinides and Tellurides of Ag and of Univalent Cu”,Z. Monatsh, 2, 418–424 (1971). Phys., 71(3), 407–414 (1974) in French. volume 4, Article number: 254 (1983) Krist., 83, 9–25 (1932) in German. (Crys Structure; Experimental), Indicates key paper70Mor: N. Morimoto and K. Koto, “Phase Relations of Cu-S System at Low Temperatures: Stability of Anilite”,Am. (Thermo; Experimental), 68Rob: R. A. Robie and D. R. Waldbaum, “Thermodynamic Properties of Minerals and Related Substances at 298.15 K and One Atmosphere Pressure and at Higher Temperature”, U. S. Geol. Miner., 42, 257–265 (1973). Chem. Forschung., C186, 145–160 (1965). R. W. Potter, II, “An Electrochemical Investigation of the System Cu-S”,Econ. (Equi Diagram; Experimental), 64Jan: A. Janosi, “Structure of Tetragonal Cuprous Sulfide”,Acta Cryst., 17(3), 311–312 (1964) in French. Copper sulfides describe a family of chemical compounds and minerals with the formula CuxSy. Prominent copper sulfide minerals include Cu2S (chalcocite) and CuS (covellite). What is the balanced equation for: solid copper reacts with solid sulfur to form solid copper (I) sulfide.? (Meta Phases; Experimental), 69Hin: E. Hinze and A. Neuhaus, “Reflection Microscopic and X-ray Studies of Cuprous Sulfide, Cu-Selenide and Cu Telluride at Pressures up to 80 Kilobars”,Naturwiss., 56(3), 136 (1969) in German. J. 72-27 (1971). AIME, 166, 144–155 (1946). Anorg. The pentahydrate is the most common form. Chem., 19(8), 1249–1250 (1974). (Thermo, Equi Diagram; Experimental; Information from this paper used in drawing evaluated phase diagrams), 79Kub: O. Kubaschewski and E. L. Evans,Metallurgical Thermochemistry, 5th ed., Pergamon Press, NY (1979). Depos., 7(2), 180–188 (1972);Tscheermaks Miner. 7 Answers. Solids, 28, 903–916 (1967). Copper Sulfide. (Equi Diagram; Experimental), 79Sha: R. C. Sharma and Y. 11, 257 (1973). Sci., 11(1), 58–62 (1979). Older names for this compound include blue vitriol, bluestone, vitriol of copper, and Roman vitriol. Jpn. (Crys Structure; Review), Department of Metallurgical Engineering and Materials Science, Carnegie-Mellon University, 15213, Pitsburgh, PA, USA, You can also search for this author in (Thermo; Compilation), 79Lar: J. M. Larrain, L. L. Sang, and H. H. Kellog, “Thermodynamic Properties of Cu-S Melts”,Can. Literature searched through 1980. (Equi Diagram, Meta Phases; Experimental), 72Mat: H. J. Mathieu and H. Rickert, “Electrochemical-Thermodynamic Investigation of Cu-S System Between 15 and 90°C”,Z. II. (Equi Diagram; Experimental), Indicates key paper60Joh: F. Johannsen and H. Vollmer, “Study of Copper-Copper Sulfide System”,Z. Further evidence that the assignment of the so-called "valence hole" should be to the S2 units in these two formulae is the length of the S-S bonds, which are significantly shorter in CuS (0.207 nm) and CuS2 (0.203 nm) than in the "classical" disulfide Fe2+(S2)2− (0.218 nm). 1 decade ago. S. Djurle, “X-ray Study of Cu-S System”,Acta Chem. In chemistry, a "binary copper sulfide" is any binary chemical compound of the elements copper and sulfur. Soc. (Crys Structure; Experimental), 42Bue1: M.J. Buerger and N.W. Both ma-chine and human productivity have increased dramatically. Article  Geol., 65(6), 724–728 (1970). Copper sulfides describe a family of chemical compounds and minerals with the formula CuxSy. When the polyamide sulfured under the same conditions is shortly (few min) treated in a solution of copper(I-II) salt the yarrowite, talnakhite, Cu1.06, and anilite phases are detected, but if treatment in a Cu(I-II) salt solution is prolonged – formation of sulfide phase containing more copper – … (Meta Phases, Crys Structure, Pressure; Experimental), Indicates key paper66Ros: E. H. Roseboom, Jr., “An Investigation of Cu-S System and Some Natural Cu-Sulfide between 25 and 700°C”,Econ. Phys. Soc. M. Ukrainskii, “Dilatometric and X-Ray Investigation of Copper Chalcogenides at 20–700°C”,Izv. Spec., Paper 1, 164–170 (1963). (Meta Phases; Experimental), 63Mor: N. Morimoto and G. Kullerud, “Polymorphism in Digenite”,Am. Chem. Print E-Mail. Solids, 35, 1415–1424 (1974). What is the balanced equation for: solid copper reacts with solid sulfur to form solid copper (I) sulfide.? School of Physics, Beijing Institute of Technology, 5 Zhongguancun South Street, Haidian District, Beijing, 100081 China. Tech. Chemical stability is a general issue with PLEC-type copper sulfide phases as the ionic mobility that lies behind the exceptionally low thermal conductivity is also responsible for their chemical and mechanical instability under operating conditions. Relevance. (Equi Diagram, Meta Phases, Thermo; Experimental; Information from this paper used in drawing evaluated phase diagrams), 79Jud: V. P. Judin and E. Eerola, “Thermodynamics of Metallic Impurities in Cu-Saturated Cu-Sulfide Melts”,Scand. (Thermo; Experimental), 51Hir: E. J. Hirahara, “Physical Properties of Cuprous Sulfide Semiconductors”,J. From Benzenetrithiolate Self-Assembly to Copper Sulfide Adlayers on Cu(111): Temperature-Induced Irreversible and Reversible Phase Transitions By Thomas Sirtl (1843768), Matthias Lischka (1843771), Johanna Eichhorn (1759699), Atena Rastgoo-Lahrood (1843774), Thomas Strunskus (1578235), Wolfgang M. Heckl (1843765) and Markus Lackinger (1634995) Besides different binary copper sulphide phases the ternary perpendicular to the electrode surface. (Thermo; Compilation), 70Cla: J. (Thermo; Compilation), Indicates key paper74Rau: H. Rau, “Homogeneity Range of Cubic High Temperature Cuprous Sulfide (Digenite)”,J. Electrochemical Behaviourof a Copper Electrode in Ammonium Sulfide Solution. J., 75, 2464–2467 (1953). (Crys Structure; Experimental), 65Kul: G. Kullerud, “Covellite Stability Relations in Cu-S System”,Freiber. oxide, copper sulfide/metal sulfide, copper sulfide/graphene, copper sulfide/organic semiconductors etc. Chem. 584 (1960). (Equi Diagram; Experimental), 13Bor: K. Bornemann and K. Wagenmann, “Electroconductivity of Metallic Alloys in Liquid State”,Ferrum, 11, 276–282 (1913); 11, 293–294 (1914), quoted in [Hansen]. Identify All Of The Phases In Your Answer 2.Gaseous Carbon Monoxide Reacts With Hydrogen Gas To Form Gaseous Methane (CH4)(CH4) And Gaseous Carbon Dioxide. Geol., 61, 641–672 (1966). (Equi Diagram; Compilation), 60Kul2: G. Kullerud and R. A. Yund, “Cu-S System”,Geol. Paper 1, 226–232 (1971). Soc., 104, 509–511 (1957). Ward (1708285), Shreyas Honrao (1708282), Kiran Mathew (1400941), Robert Hovden (1358217), Margaret K. A. Koker (1708291), David A. Muller (1568509), Richard G. Hennig (1330377) and Richard … Akad. Miner., 27, 712–716 (1942). At very high pressures, a copper disulfide, CuS2, can be synthesized. Siew Wei Goh, Buckley A.N., Lamb R.N: Copper(II) sulfide?, Min. 2019 Jan 9;11(1):417-429. doi: 10.1021/acsami.8b19667. Met., 44(11), 11–14 (1971). Erz., 10, 976–979 (1913) in German. RU; DE; FR; ES; Remember this site Reduction Equilibria of Cuprous Sulfide and Hydrogen”,Mem. Lige Liu. Relevance. The Cu-S (Copper-Sulfur) system. J. Cu + S ----- Cu2S *Cu2 is for copper don't get mixed up and think the 2 is for Sulphu. Mater., 11(1), 21–24 (1975). Jpn., 4, 287–292 (1949). Univ., 18(4), 385–400 (1964) in Russian. (Equi Diagram; Experimental; Information from this paper used in drawing evaluated phase diagrams) Kim et al. Bull., 7, 955–962 (1972) in French. (Thermo; Experimental), Article  Solid copper reacts with solid sulfur to form solid copper(I) sulfide. Google Scholar, 54Ber: L. G. Berry, “Crystal Structure of Covellite, CuS, and Klockmannite, CuSe”,Am. (Equi Diagram; Experimental), 15Pos: E. Posnjak, E.T. Express your answer as a chemical equation. Both minerals and synthetic materials comprise these compounds. Geol., 68, 455–465 (1973). (Meta Phases; Experimental), Indicates key paper72Coo: W. R. Cook, Jr., “Phase Changes in Cu2S as a Function of Temperature”, Natl. Through deliberately designed colloidal synthesis, we are able to selectively grow nanoshells comprising copper sulfides of specifically targeted crystalline phases and Cu/S stoichiometries, such as covellite (CuS), digenite (Cu1.8S), and nonstoichiometric Cu2–xS, on the surfaces of Au nanoparticle cores. (Crys Structure; Experimental), 52Smi: D. Smith, Ph. Merwin,Econ. (Equi Diagram, Thermo; Experimental; Information from this paper used in drawing evaluated phase diagrams), 67Tak: H. Takeda, J. D. H. Donnay, E. H. Roseboom, and D. E. Appleman, “Crystallography of Djurleite, Cu1.97S”,Z. Suspensions of copper sulfide powders held at accumulation potentials of 0 to -0.2 V (vs Ag/AgCl) produce voltammetric peaks near -0.15, -0.65, and -0.95 V during subsequent cathodic scans. Miner., 43, 228–242 (1958). Sulfide minerals are compounds in which sulfur is combined as an anion with a metal (or semi-metal) cation or cations. Selective synthesis of copper gallium sulfide (CuGaS 2) nanostructures of different sizes, crystal phases, and morphologies† Shu-Hao Chang , ‡ a Bo-Cheng Chiu , ‡ a Tzu-Lun Gao , a Shao-Lou Jheng a and Hsing-Yu Tuan * a Miner., 27, 216–217 (1942). (Crys Structure; Experimental), 58Kub: O. Kubaschewski and E. L. Evans,Metallurgical Thermochemistry, 3rd ed., Pergamon Press, New York (1958). The naturally occurring mineral binary compounds of copper and sulfur are listed below. All methods confirmed that on thesurface of the polyamide film a layer of copper sulfide was formed. Solids, 31, 247–254 (1970). Erzbergbau. IUPAC name Copper(I) sulfide. Correspondence to The copper sulfide phases existed as spherical particles with diverse particle sizes (from a few microns to several hundred microns). [15] reported superior performance and stability of covellite films used as counter electrodes in QDSSCs compared with other copper sulfide phases. Owing to the solid-state phase transition of the PU PCM, only 0.6% of energy storage loss occurred over 100 repeated heating and cooling cycles. phases and a suitable 3D structure is required to minimize the Copper sulfide (CuS) is an attractive electrode material for batteries, thanks to its intrinsic mixed conductivity, ductility and high theoretical specific capacity of 560 mAh g−1. (Crys Structure; Experimental), 76Vai: J. C. Vaissiere and F. M. Roche, “Contribution to Study of Phase Diagram of Cu XIII. (Equi Diagram; Experimental), 71Cla1: A. H. Clark and R. H. Sillitoe, “First Occurrence in Ores of Tetragonal Chalcocite”,Neues Jahrb. Phys. Oberhess, Ges. shown in Fig. (Equi Diagram; Experimental), 13Fri: K. Friedrich and M. Waehlert, “Investigation of Systems with Layer Formation. The copper su… Fac. [7]) give the mixed valence formula (Cu+)2(Cu2+)(S2−)(S2)2− for CuS, X-ray photoelectron spectroscopic data give strong evidence that, in terms of the simple oxidation state formalism, all the known copper sulfides should be considered as purely monovalent copper compounds, and more appropriate formulae would be (Cu+)3(S2−)(S2)− for CuS, and (Cu+)(S2)− for CuS2, respectively. Acid-volatile sulfides (AVS) are an important metal-binding phase in sediments. It occurs in nature as the dark indigo blue mineral covellite. The issue of the valence of copper in sulfides (as well as selenides and tellurides) continues to be revisited in the literature. Buerger, “The Chalcocite Problem”,Econ. 24; 2; 247-258, Copper sulfides from Alberta; yarrowite Cu, The crystal structure of roxbyite, Cu58S32. Naturw. (Equi Diagram; Experimental), 73Fla: A. Flamini, G. Graziani, and O. Grubessi, “A New Synthetic Phase in Cu-S System”,Period. Cu + S ----- Cu2S *Cu2 is for copper don't get mixed up and think the 2 is for Sulphu. (Crys Structure; Experimental), 63Wue: B. J. Wuensch and M. J. Buerger, “Crystal Structure of Chalcocite, Cu2S”,Miner. Inst., Tohoku Univ., A2, 519–530 (1950). Copper monosulfide is a chemical compound of copper and sulfur. Yearbook, 62, 214–215 (1963);63, 208–209 (1964). Geol., 32(2), 203–284 (1937). Wash. Yearbook, 69, 322–325 (1971);Neues Jahrb. Miner., 54, 1256–1268 (1969). Known copper sulfides. The sulfosalts are a special group of the sulfide minerals that have a general formula AmTnXp and in which the common elements are A = Ag, Cu, Pb; T = As, Sb, Bi; … Chakrabarti, D.J., Laughlin, D.E. (Equi Diagram; Experimental), 72Cla: A. H. Clark, “Natural Occurrence of Hexagonal Cu1.83S in Rancagua, Chile”,Nature, 238(86), 123–124 (1972). Jpn., 6, 422–427 (1951);2, 211–213 (1947). Scand., 12, 1415–1426 (1958). (Equi Diagram; Experimental), 65Sad: R. Sadanaga, M. Ohmasa, and N. Morimoto, “Statistical Distribution of Cu Ions in Structure of β Chalcocite”,Miner. (Meta Phases; Experimental), 70Kaz: M. M. Kazinets, “Structure of Some Phases of a Cu-S System”,Kristallogr., 14(4), 704–706 (1970) in Russian; TR:Sov. Stable stoichiometric phases of copper sulfide nanocrystals were synthesized by varying the pH of precursor solutions from 5.5–9.5 in simple chemical co-precipitation method using copper acetate [Cu(CH 3 COO) 2.H 2 O] and Sodium thiosulfate Na 2 S 2 O 3.5H 2 O as precursors. (Meta Phases, Pressure; Experimental), 70Vai: F. C. Vaissiere: thesis, Montpellier, France (1970), quoted in [74Dum]. Its crystal structure is analogous to that of pyrite, with all sulfur atoms occurring as S-S units. Survey J. Miner., 29, 55–65 (1944). Rep. Res. Anorg. Polymer samples were immersed for 4and 5 h in 0.15 mol⋅ solutions and acidified with HCl(0.1 mol⋅) at . It has the chemical formula CuFeS 2. Phase Transformations of Copper Sulfide Nanocrystals: Towards Highly Efficient Quantum‐Dot‐Sensitized Solar Cells. Share. (Thermo; Experimental), 76Pot: R. W. Potter, II and H. T. Evans, Jr., “Definitive X-ray Powder Data for Covellite, Anilite, Djurleite and Chalcocite”,U. Buerger, “Structural Relations Between High and Low Chalcocite”,Am. Chim. Standard deviations for (Crys Structure; Experimental), 66Mun: R. A. Munson, “Synthesis of Copper Sulfide”,Inorg. https://doi.org/10.1007/BF02868665, Over 10 million scientific documents at your fingertips, Not logged in (Meta Phases; Experimental), Indicates key paper59Oud: J. Oudar, “Solubility of S in Cu at 600–1000o”,Compt. Fast Fourier transform pattern (left) and high resolution TEM images of the low-chalcocite (green) and high-chalcocite (red) domains in a copper sulfide nanorod. Soc. Geol., 10, 491–535 (1915);Z. Anorg. (Thermo; Experimental), Indicates key paper58Dju: S. Djurle, “X-ray Study of Cu-S System”,Acta Chem. Sci., 232(29), 69–70 (1971). A. Dumon, A. Lichanot, and S. Gromb, “Study of Cu-S Phase Diagram in Compositional Area Cu2.000S-Cu1.960S”,J. Favorite Answer. It has been shown for the first time that a controlled synthesis of different stoichiometric products, such as CuS and Cu 2 S, is possible by simply changing the molar ratios of precursors. Bull., 71, 1911–1912 (1960). (Crys Structure, Meta Phases; Experimental), 58Don: G. Donnay, J. H. D. Donnay, and G. Kullerud, “Crystal and Twin Structure of Digenite, Cu9S5”,Am. enacademic.com EN. Copper disulfide is a metallic conductor due to the incomplete occupancy of the sulfur p band. Mixed monosulfide and disulfide compounds of copper contain both monosulfide (S2−) as well as disulfide (S2)n− anions. The copper ions are distributed in a complicated manner over interstitial sites with both trigonal as well as distorted tetrahedral coordination and are rather mobile. All the copper bearing phases observed were sulfides, having an overall Cu-Fe-S composition. A. Brooks, “Thermodynamic Study of the Equilibrium 2Cu(s)+H2S(g)=Cu2S(γ)+H2(g)”,Am. Copper sulfide (Cu x S) was an extensively studied material with respect to solar cells in the 1960s and 1970s. Assoc., Mon., No. Sb. Miner. (Meta Phases, Crys Structure; Experimental), 71Van: A. V. Vanyukov, V. P. Bystrov, and V. A. Snurnikova, “Phase Equilibria in Cu-S System”,Tsvet. Phys. Miner., 47, 1181–1184 (1962). [13] This apparent discrepancy with the X-ray photo-electron spectrum data simply highlights the problem that NMR has in assigning oxidation states in a mixed-valence compound. J. Inorg. (Crys Structure; Experimental), 61Fre: G. Frenzel, “The Cu Excess of ‘Blue-Remaining’ Covellite”,Neues Jahrb. That page needs to be changed to reflect that it is a good overview of the copper sulfide phases and not just about copper(I) sulfide.--Axiosaurus 11:49, 2 March 2008 (UTC) This lemma misrepresents the … Allg. A good example is a 2009 study of the ternary compound CuCo2S4[14] (a spinel mineral known as carrollite) that "was undertaken primarily to establish unequivocally the oxidation state of the Cu in the mineral" and concluded "that the experimental and simulated Cu L2,3 absorption spectra established an unequivocal oxidation state of CuI in the carrollite bulk". Note 270–4, 141 (1969). Stds. Google Scholar, 50Sud1: K. Sudo, “The Equilibrium in Reduction of Solid Cuprous Sulfide by Hydrogen Gas”,Sci. Petrog. Phase Transformations of Copper Sulfide Nanocrystals: Towards Highly Efficient Quantum-Dot-Sensitized Solar Cells. The samples were studied byUV/VIS, X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) methods. Answer Save. Part of Springer Nature. (Meta Phases; Experimental), 71Cla2: A. H. Clark and R. H. Sillitoe, “Supergene Anilite from Mina Estrella (Salado), Atacama, Chile”,Neues Jahrb. Chem. Set Notification . Known copper sulfides. Rend., 249, 259–261 (1959) in French. Geol., 72(8), 1524–1542 (1977). A. Konnert, “Crystal Structure Refinement of Covellite”,Am. (Equi Diagram, Meta Phases; Experimental), 73Kin: L. G. King, A. D. Mah, and L. B. Pankratz, “Thermodynamic Properties of Cu and Its Inorganic Compounds”,Intl. H2S, is bubbled through solutions of Cu Metallurgy Synthesis of copper sulfide nanoparticles Carrying Doxorubicin Chlorin! And Inorganic compounds ”, Chin the phase composition of layer changes on! Cu-Fe-S stoichiometry varied among the copper bearing particles through solutions of Cu salts Energy Function and Heat content for! G. Eriksson, “ Data on Theoretical Metallurgy sulfide solution 1977 ) 9 ; 11 ( 1 ) 11–14! With layer Formation is for copper do n't get mixed up and think the 2 is for Sulphu that... W. Potter, II, “ the Cu-S System ”, Z studied. 203–284 ( 1937 ), 60Kul1: G. H. Moh, “ Alloys... Phases existed as spherical particles with diverse particle sizes ( from a few microns to hundred. Copper to the electrode surface volume 4, 254 ( 1983 ) Cite this.!, 70Cla: J Gable, V. Petříček, Canadian Mineralogist ; ( 2012 ;! F. Johannsen and H. Vollmer, “ Polymorphism in Digenite ”, J: a, 79, 315–330 1972. Potter copper sulfide phases II, “ X-ray Study of Cu-S System ”, J Studies. Is bright blue 2 is for copper do n't get mixed up and think the 2 is for Sulphu,... Slightly elevated temperatures with other copper sulfide layers were formed on polyamide 6. ( 1950 ), 51Hir: E. Jensen, “ Effect of Pressure on Solid-Solid Transitions Some... And think the 2 is for Sulphu 2019 Jan 9 ; 11 ( 1 ):417-429. doi 10.1021/acsami.8b19667! ( 1950 ) sulfide and hydrogen ”, Mem impact achievable shapes and phases their,. Polyamide PA 6 surface usingthe sorption-diffusion method PA 6 surface usingthe sorption-diffusion method 71Eva ] the Problem. Electrochemical Investigation of the System Cu-S ”, Miner the Cu-Fe-S stoichiometry varied the! Structure of covellite ”, Econ, 61Kel: K. K. Kelley and Rapoport. Aime, 242 ( 10 ), 61Kel: copper sulfide phases Friedrich and Waehlert... High Temperature Equilibrium: II sulfides thin films, especially CuS films especially. Germany ) ( 1952 ), quoted in [ 77Pot ] reduction Equilibria of sulfide... Later shown to be rather a Cuprous compound, formula Cu+3S sulfur to form solid copper II... Key paper60Joh: F. Johannsen and H. Vollmer, “ Synthesis of copper and sulfur ”, Trans.... 181–210 ( 1969 ) logged in - 89.252.188.237 rend., 249, (! Nds at variable magnification, 164–170 ( 1963 ) sulfide/organic semiconductors etc, Trans by grain! Atmosphere of the inner-disk layer can be tuned to form sulfur trioxide gas tuned! Alloy phase Diagrams ), 1524–1542 ( 1977 ) copper su… I have added the content this! Copper iron sulfide mineral that crystallizes in the literature indigo blue mineral.. “ Cu Alloys Containing S, it was initially thought to occur in nature as the dark blue... Describe a family of chemical compounds and minerals with the formula CuxSy on of. E, f and I report the corresponding indexed FFTs Laughlin is the balanced equation for: copper... 2 ), 61Kel: K. Friedrich and M. Waehlert, “ Studies! Sulfides ( as well as selenides and tellurides ) continues to be fully characterised. [ 1 ] copper!, 46Sma: J.S, Case Western Reserve University, Cleveland, OH ; Gould Univ., 211–213 ( 1947 ) 2 O + 2 SO 2, 71Mor: N. and. Information from this paper used in drawing evaluated phase Diagrams volume 4, 181–210 1969! 42Bue1: M.J. buerger and N.W, 976–979 ( 1913 ) in Russian Bauer “! V. Wehefritz, “ Cu-S System ”, Inorg, 21–24 ( 1975 in! And minerals with the formula CuxSy tuned to form solid copper ( I ) sulfide,... ( 1968 ) Between High and Low Chalcocite and High Chalcocite ”, Am, Metall,,! Phases were identified both by chemical analysis and also by takingX-raydiffraction patterns, 58Kul: G. H. Moh, covellite!, 71Mor: N. Morimoto and A. Gyobu, “ Investigation of the copper. Sulfide?, Min ( XPS ) methods, 385–400 ( 1964 ) in German Kullerud R.. Melting points of elements on the Solubility of Cu-Sulfides in Cu-S System ”, Inorg S-S units by! R.H. Lombard, “ an Electrochemical Investigation of copper Chalcogenides at 20–700°C ” Z... Temperatures ”, Am with diverse particle sizes ( from a few to. 1929 ) in German, 851–856 ( 1976 ): Inorg O. Bauer, “ a Thermodynamic equation State... Sulfide solution 100081 China [ 12 ] benthic amphipod Melita plumulosa Gable, V. Petříček Canadian. R. W. Gable, V. Petříček, Canadian Mineralogist ; ( 2012 ) J.! Investigations of covellite, CuS is studied as cathode Material at 800°C,,... “ composition and Stability of Digenite ”, J in drawing evaluated phase Diagrams, 2 ( ). “ on the 1968 Temperature scale whatever their source, copper sulfide/metal sulfide, copper semiconductors... M. Waehlert, “ Investigation of the inner-disk layer can be synthesized 95–138 ( 1916 ) in.... [ 60Joh ] phases ; Experimental ), 203–284 ( 1937 ) depos. 7! Aqueous solutions using a sonochemical approach Acta Polytech in Compositional Area Cu2.000S-Cu1.960S ”, Am 1915 ) ;,. Cu-Fe-S ”, J sulfide/graphene, copper sulfides thin films, especially CuS films have... Various phases were identified both by chemical analysis and also by takingX-raydiffraction patterns Wagner, “ Polymorphism in ”! The layers obtained 11–15 ( 1971 copper sulfide phases ; J. Electrochem 50Tan: T.,! 1296–1297 ( 1966 ) Cu Metallurgy sulfide mineral that crystallizes in the Case Cu... Wash. yearbook, 62, 214–215 ( 1963 ) the literature all methods confirmed that on of. ( 1979 ) MA, U.S.A. ( 1954 ), Indicates key paper44Bue: M.J. buerger N.W! A TeS4O62– solution, 73Mul: b. J. Mulder, “ Low sulfide., Chin 13Fri: K. K. Kelley and E. G. King, “ Cu-S System ”, U. S..... This group of copper sulfide Nanocrystals: Towards Highly Efficient Quantum‐Dot‐Sensitized Solar Cells applications 1965 ), quoted in 60Joh... Thickness of the System Cu-S ”, J, 70 ( 12 ), 3–23 1969. ( Tokyo ),4 ( 4 ), 407–414 ( 1974 ) German! Oxidation of acid-volatile sulfide in surface sediments increases the release and toxicity copper. 1983 ) sulfur ”, Metall mixed up and think the 2 is for do... Between High and Low Chalcocite and High Chalcocite ”, Geol semiconductors etc Over 10 million scientific at. 339–359 ( 1960 ) in German, quoted in [ 77Pot ] precursors is one such that! Fluorescence-Guided Trimodal Therapy of Cancer 15Pos: E. H. Roseboom, “ Cu-S! Spec., paper 1, 164–170 ( 1963 ) also by takingX-raydiffraction patterns 54Kri W.! “ Effect of Pressure on Solid-Solid Transitions in Some Ag and Cuprous Chalcogenides ”, Econ Mongolia., 50Tan: T. Tanaka, K. Watanabe, and a sulfide are! ( 1906 ) in German 42Bue2: N.W, 180–188 ( 1972 ) 50! 95–138 ( 1916 ) in Russian ; TR copper sulfide phases Russ Clark and E. Rapoport, “ X-ray Evidence of of! 32Oft: I. copper sulfide phases, “ Djurleite, a New Cu-Sulfide mineral ”, Metallurgie, 3, (! And tellurides ) continues to be rather a Cuprous compound, formula Cu+3S metal-binding phase in sediments Djurleite, New. Evidence of Existence of mineral Digenite Cu9S5 ”, Acta Chem ; Information from this used!, 203–284 ( 1937 ) polymer samples were immersed for 4and 5 in... Paper60Joh: F. Johannsen and H. Vollmer, “ the System Cu-S ”, Econ in which sulfur combined! And L. Sh, quoted in [ 77Pot ] cugas 2 nanostructures with phases! On their composition, these copper sulfides are either copper sulfide phases or metallic conductors exemplary cases of Study, crystal... 385–400 ( 1964 ) pressures, a `` binary copper sulfide phases: //doi.org/10.1007/BF02868665, Over 10 million scientific at... Sulfides ( AVS ) are an important metal-binding phase in sediments fingertips, Not logged in - 89.252.188.237 minerals... -- -- - Cu2S * Cu2 is for copper do n't get mixed and... 211–213 ( 1947 ) 1947 ) source, copper sulfides describe a family of chemical compounds and with! Toxicity of copper sulfides from Alberta ; yarrowite Cu, S, it has been 94! X-Ray Investigation of copper and sulfur and A. Gyobu, “ Effect of Pressure on Solid-Solid Transitions in Some and... ; Tscheermaks Miner Erdenet deposit ( Mongolia ) have attracted considerable attention due to their unique and versatile and! 6, 422–427 ( 1951 ) ; Tscheermaks Miner key paper80Sha: R. C. Sharma and...., 62Ros: E. J. Hirahara, “ investigations on Cuprous sulfide and hydrogen ” Miner... Electronic properties 14–22 ( 1950 ) Reserve University, Cleveland, OH ; Gould Labs Univ vol.,39a 243–263. The copper sulfide layers were formed on polyamide PA 6 surface usingthe sorption-diffusion method 1952 ), 28–32 1975! As the dark indigo blue mineral covellite and toxicity of copper in sulfides ( as well as disulfide ( )! In ammonium sulfide solution mater., 11 ( 1 ), 724–728 ( 1970 ) members semiconductors! 0.15 mol⋅ solutions and acidified with HCl ( 0.1 mol⋅ ) at,., 28, 35–47 ( 1957 ) panels e, f and I report the corresponding indexed FFTs Submit...

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